3. 강의목표
With emphasis on structure, bonding, properties, and reactivities, we will explore the frontiers of molecular inorganic chemistry. Starting with organotransition metal species, the class will cover main-group materials, bioinorganic active sites and their models, and supramolecules.
4. 강의선수/수강필수사항
Undergraduate level inorganic/organic chemistry.
5. 성적평가
| 중간고사 |
기말고사 |
출석 |
과제 |
프로젝트 |
발표/토론 |
실험/실습 |
퀴즈 |
기타 |
계 |
| 25 |
25 |
10 |
|
25 |
15 |
|
|
|
100 |
| 비고 |
1) Attendance (10%)
2) Midterm Exam (25%) : In-class
3) Presentation (15%): Literature presentation on selected topics on molecular inorganic chemistry
4) Final Exam (25%) : In-class; Final Exam will emphasize topics discussed since Midterm
5) Original Proposal (25%): A research proposal on Molecular Inorganic Chemistry
- Includes a 5-min flash talk
- JACS Communication format
- No longer than 2-pages excluding references
|
7. 참고문헌 및 자료
Recommended books for reading (No required textbook for the class)
Exploring Chemistry with Electronic Structure Methods
Organotransition Metal Chemistry: From Bonding to Catalysis by John Hartwig
Espenson, James, H. “Chemical Kinetics and Reaction Mechanisms” 2nd Edition. ISBN 0072883626 (available in the library)
Tobe, Martin L.; Burgess, John “Inorganic Reaction Mechanisms” (available in the library)
Jordan, Robert B. “Reaction Mechanisms of Inorganic and Organometallic Systems” 3rd Edition. (Library) (available in the library)
Wilkins, Ralph G. “Kinetics and Mechanisms of Reactions of Transition Metal Complexes” 2nd Edition. (Library) (available in the library)
8. 강의진도계획
LECTURES:
We meet on Tuesday and Thursday from 11:00 AM –12:15 PM in room 310, located in the chemistry building.
L1. Course Introduction
L2. Intro to Molecular Inorganic Chemistry
L3. P-table; electronegativity; Lewis structures; valence e– counts; oxidation states; line notation
L4. Ligands; cone angle; tolman electronic parameters; chelate effect; hapticity; bridging ligands;
L5. Coordination geometries; bonding; orbitals; 18 e– “rule”; metal–metal bonding
L6. Intro to organotransitionmetal chemistry; historical perspective
L7. Ligand substitutions
L8. Oxidative addition; reductive elimination
L9. Intramolecular insertion; elimination
L10. Hydrogenation
L11. Carbonylation
L12. Polymerization, cyclization
L13. Cross-coupling
L14. Carbenes, metathesis
L15. Ligands in MG chemistry; carbenes; N-heterocyclic carbenes; carbones
L16. Heavier carbene analogs; Drago’s rule; phenyl and terphenyl ligands; Grignard reagent; coordinating solvents
L17. Push–pull stabilization; electron counting recap; MG–MG multiple bonding; crown ethers; cryptand; reducing reagents
L18. Homo and heteronuclear bonding; Wiberg bond index; metal hydrides;
L19. Chemistry of each group; periodic trend
L20. Active sites; structural modelling; hemoglobin; myoglobin; hemocyanin; hemerythrin; vitamin B12;
L21. Fe–S clusters; carbonic anhydrase; hydrogenase; oxygenase; oxidase; vitamin B12
L22. Inorganic spectroscopies
L23-L25. Supramolecular chemistry
9. 수업운영
This is a graduate level course but I strongly recommend senior undergraduate students to take this class, especially those who are interested in synthetic chemistry. This class will cover basic organometallic, bioinorganic, main-group, and supramolecular chemistry with emphasis on structure, bonding, properties, and reactivities.
10. 학습법 소개 및 기타사항
The lecture will be given in English.
11. 장애학생에 대한 학습지원 사항
- 수강 관련: 문자 통역(청각), 교과목 보조(발달), 노트필기(전 유형) 등
- 시험 관련: 시험시간 연장(필요시 전 유형), 시험지 확대 복사(시각) 등
- 기타 추가 요청사항 발생 시 장애학생지원센터(279-2434)로 요청